Fuelly

Saturday, February 11, 2012

Faster Initial Charging and CellLog8

Episode 02 of my video blog:


While charging the first cell, it quickly became clear that the 5A output of the bench power supply wasn't enough to get charging done in a sensible amount of time.  The cells appear to be delivered with 50% charge and so I have to put another 200Ah into them.  At 5A, this would take 40 hours at least.

I'd also had some concern expressed by Jack Rickard about such a slow charge rate being effectively a trickle charge that might not even be able to push the cells to the top and could even overcharge them in some way by trying for too long.

There was some conflict in advice, in that Jack has been using these cells for a couple of years and has never done an initial charge on them and never charges them to 4.00V.  His method is to stop charging at 3.60-3.65V (but often charging the cells in series), safely under charging them, with no active BMS present (or required).  I take his advice seriously, as he's tested lots of cells in his lab and blown up a few when over charging them on the bench!

However, the Winston Battery operator's manual is quite clear (and insistent) that this initial charge to the full 4.00V is done before the first discharge.  GWL echoed this in their user FAQs.  So I contacted the Technical Manager at GWL for advice on whether I should do the initial full charge, whether the 5A bench PSUs are suitable and whether any harm comes of doing the initial charge too slowly.  The Winston Battery manual recommends a charge rate of between 0.1CA and 0.5CA, but this is out of my reach as it means a PSU that can deliver between 40A and 200A!

The response from GWL was go with the full 4.00V CC-CV cycle and it's ok to do it slowly, so long as you terminate the cycle properly when the current has reduced in the CV phase.  They have posted a technical paper (PDF) warning about using shunt BMS systems that hold cells for too long at the terminal Voltage (4.00V). However, this was in the context of holding cells at that Voltage for long (cumulative) periods after the charge acceptance current of that cell has effectively reached nothing.  Not the same case as doing a very slow charge and terminating at the end of charge acceptance of the cell.

So, on balance, I'm going with the advice of the manufacturer and the supplier of the cells on this.  At least that way, if it turns out to be bad advice, they are on the hook for giving it to me - if it comes to a warranty claim.
I'm using these new 80W constant power SMPS PSUs from Maplins.  They can run in parallel with a master/slave link and they also have a remote sense input so that the constant Voltage dialed in is measured at the cell terminals and can compensate for the Voltage drop in the heavy current power leads.  This way you dial in 3.97V and you know the charger will hit the mark.

The unit is small, light and efficient.  Doesn't get hot in use, has no need of a fan and is power factor corrected.  At £100 each, they're not cheap but also checking RS, Farnell and Rapid didn't turn up anything better value.

After the initial charge, the manual advises that it's ok to subsequently charge within any part of the cells safe operating range from 2.50V to 4.00V.  So I'll adopt Jack's strategy of making sure all the cells are bottom balanced (at 2.75V when "empty") and then never fully charging them, to avoid the problems and need for active top balancing and current shunting and all that expensive and failure prone junk.

The CellLog8 should be all I need to prevent over discharge of the pack or individual cells in the pack.  It can monitor each cell individually and I can set an alarm for any cell that goes below 3.00V or the whole pack goes below 24.0V.  It can also alarm if any cell differential Voltage (the difference between individual cells) exceeds a limit.  This will tell you if the pack is out of balance -even before it gets to being near full or empty.  The CellLog8 has a beeper and an open collector transistor output that can be used to provide an "inhibit" signal to my inverter to shut it down until the solar array can recharge the pack.

Of course, the required 9 pin header cable for the CellLog8 didn't come with the thing, so I had to source that from a radio control models shop (Electriflyer).  They also sell the Junsi lithium battery chargers that use the same JST-HX balance lead (model BW-9-11).  Just under £5 delivered.
The cable is actually meant to connect a Junsi iCharger 208b charger to a balance board (hence the 11 way header on the other end) but you can either cut off the big plug or use it.  The CellLog8 doesn't have a proper JST socket so a plug with more than 9 pins will fit;  the spare ones will stick out over the end of the 9 pin header on the device.  I might cut the lead in the middle and then have two usable plugs for the gadget.
Another thing I had to order was some terminal lugs.  These are also a bit harder to track down because they are M14 stud holes.  I found some on eBay from Clarik Engineering Supplies.  They take up to 120mm2 cable (too big for my 35mm2 cable).  I might have to use a blow torch or my pipemaster plumbing soldering iron to attach cable to them.  These alone were another £7 delivered... Everything is expensive when you have such massive terminals on a battery!

Tuesday, February 7, 2012

Unboxing the Beasts

The Winston Battery cells are expensive. This lot of 8 cost me an eye-watering €4096 which translated into £3540 including 20% VAT 2% credit card payment surcharge, 2.5% currency exchange charge (from VISA as it was in Euros to Pounds) and TNT overland shipping (quite quick at 3 days from Prague).  At least when I put the payment in it was the week when all the Euro countries got their credit ratings downgraded and the Euro slumped against Sterling.

Pretty steep, but actually a lot cheaper than good OPz solar cells.  A quick check on the Tanya battery web site shows "12 OPzV 1400 Sonnenschein A600 Solar Battery" cells of 1,400Ah (C100) would cost £822 each (inc VAT but excluding delivery). That's £9,864 for 12 cells to make an equivalent 24V sealed type of lead acid battery pack that might last 10 years and be usable indoors (not a flooded fork lift type battery).

Even the Deka Solar gel batteries were quoted to me at £250 each - £1,000 for 180Ah (C5).  And they only lasted 850 cycles or 2.5 years (although they were 2nd hand when I got them for £50 each, so I can't complain).

Then there's the problem of weight... the A600 bank of cells weigh 97kg each... 1,164kg in total. By comparison, the Winston Battery cells only weigh 14kg for a total pack weight of 112kg.  Even boxed as a whole pack it would be an easy two-man lift.

Just starting to play around with the video recording on my Samsung Galaxy SII phone. So, here's my first video blog entry for this lithium battery project... Enjoy!
Each cell has a factory date code and serial number printed on it.  All the cells I have are in serial number order from 6288-6295 and were all made in October 2011.
I ordered some cell connecting straps with the cells that come with the A2 grade stainless steel M14 2.0mm pitch thread terminal bolts.  You have to order the straps as the cells don't come with bolts.  The sets also include a stainless steel washer and a spring washer.

I only ordered 7 straps (as that's all you need to connect together 8 cells) but the kit rather unhelpfully doesn't include the two additional bolts you need to make the end plus and minus terminal connections.  So I had to source these from a fastening specialist in the UK (Westfield Fasteners).

I ordered:
2x A2_Screwbolt_HexHd_M14_20_THRfull (M14 x2.0 x 20mm fully threaded hex head set screw bolt)
2x A2_Washer_FormA_M14 (large diameter M14 washer - there are 3 kinds of washer)
2x A2_Washer_SprgSq_M14 (a square profile spring washer)

This was £8.75 delivered.

The cell straps themselves are a bit comedy.  They're made from multiple copper plates that have been stamped out and then tied together with heat shrink tube.
 The other thing I ordered was a Junsi CellLog8 cell logger.  This is a tiny device that is designed specifically for monitoring of multi-cell battery packs.  It can do lead, NiCd, NiMH, and all the various types of lithium cells.
What it does is monitor the individual Voltage of each of up to 8 cells (handy as I've got just that number of cells) and then you can set alarms for over, under, and differential Voltage limits on each cell and the pack as a whole.  It will beep on some / any of these conditions and also drive an open collector transistor output for a relay or whatever (either NO or NC mode).  This is going to be one of the key battery protection elements of my plan.

Monday, February 6, 2012

2012 - All Change!

Well, we're back from our adventures in Japan and while out there, I made an important decision...

I hate lead acid batteries.  They're rubbish for solar applications.

So I took the plunge and put in an order for some batteries I've been eyeing for a few months now.  They get used a lot in the DIY electric car (EV) arena because they are light, powerful, small and can withstand deep discharges daily.  What's more, they are based on lithium ion technology and so do not need or even particularly like being kept at full charge all the time, as lead acid batteries do.

In short, they are much superior to lead acid batteries in many respects (but not all).

Of the makes available, the only one that was available in Europe (let alone the UK) was the Winston Battery Company make.  These are a new sub-type of lithium ion cells that use yttrium (a rare earth metal) to significantly improve the reliability and safety of these cells, compared to the previous generation of cobalt based lithium ion cells.  These could explode violently in a ball of flames (hence the stories in the papers about exploding mobile phones and laptop batteries).
Over the next few days and weeks, I'll be getting to grips with these new cells in order to build them into a 24V nominal 400Ah battery pack for my solar system.

You can find them at the GWL EV Power shop